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High-Temperature Water Adsorption Isotherms and Ambient Temperature Water Diffusion Rates on Water Harvesting Metal–Organic Frameworks

https://doi.org/10.1021/acs.jpcc.4c01733

Hastings, Jon; Lassitter, Thomas; Zheng, Zhiling; Chheda, Saumil; Siepmann, J Ilja; Gagliardi, Laura; Yaghi, Omar M; Glover, T Grant (July 2024, The Journal of Physical Chemistry C)

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Steric and Electronic Effects on the Interaction of Xe and Kr with Functionalized Zirconia Metal–Organic Frameworks

https://doi.org/10.1021/acsmaterialslett.1c00077

Fairchild, David C.; Hossain, Mohammad I.; Cordova, Jesus; Glover, T. Grant; Uribe-Romo, Fernando J. (May 2021, ACS Materials Letters)

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Effect of cleaning methods on the dissolution of diatom frustules

https://doi.org/10.1016/j.marchem.2020.103826

Saad, Emily M.; Pickering, Rebecca A.; Shoji, Kanaha; Hossain, Mohammad I.; Glover, T. Grant; Krause, Jeffrey W.; Tang, Yuanzhi (August 2020, Marine Chemistry)
null (Ed.)
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Ionic liquids of superior thermal stability. Validation of PPh ₄ ⁺ as an organic cation of impressive thermodynamic durability

https://doi.org/10.1039/D0RA03220D

Soltani, Mohammad; McGeehee, Jimmie L.; Stenson, Alexandra C.; O'Brien, Richard A.; Duranty, Edward R.; Salter, E. Alan; Wierzbicki, Andrzej; Glover, T. Grant; Davis, James H. (May 2020, RSC Advances)

Recent work by Wasserscheid, et al. suggests that PPh 4 + is an organic molecular ion of truly exceptional thermal stability. Herein we provide data that cements that conclusion: specifically, we show that aliphatic moieties of modified PPh 4 + -based cations incorporating methyl, methylene, or methine C–H bonds burn away at high temperatures in the presence of oxygen, forming CO, CO 2 , and water, leaving behind the parent ion PPh 4 + . The latter then undergoes no further reaction, at least below 425 °C.
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